Amino Acids, Peptides and Proteins (SPR Amino Acids, - download pdf or read online

By G. C. Barrett, J. S. Davies

ISBN-10: 0854042377

ISBN-13: 9780854042371

Expert Periodical studies offer systematic and specified overview assurance of growth within the significant parts of chemical examine. Written by way of specialists of their expert fields the sequence creates a special provider for the lively examine chemist, delivering commonplace severe in-depth bills of growth particularly components of chemistry. In an ever-increasing area of task Amino Acids Peptides and Proteins presents an annual compilation of the world's examine attempt into this significant sector of organic chemistry. quantity 33 offers a overview of literature released in the course of 2000. Comprising a finished assessment of important advancements at this biology/chemistry interface every one quantity opens with an outline of amino acids and their functions. paintings on peptides is reviewed over numerous chapters starting from present developments of their synthesis and conformational and structural research to peptidomimetics and the invention of peptide-related molecules in nature. the appliance of complicated ideas in structural elucidation is included into all chapters while periodic chapters on steel complexes of amino acids peptides and beta-lactams expand the scope of assurance. effective looking out of expert themes is facilitated by way of the sub-division of chapters into discrete topic components permitting annual traits to be monitored. All researchers within the pharmaceutical and allied industries and on the biology/chemistry interface in academia will locate this an crucial reference resource.

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Extra resources for Amino Acids, Peptides and Proteins (SPR Amino Acids, Peptides, and Proteins (RSC)) (Vol 33)

Example text

The process allows the isolation of the enantiomerically pure -phenylglycine, suitable for conversion into -lactam antibiotics,468 and the pure diastereoisomers of 4-fluoroglutamine and 4-fluoroisoglutamine where prepared from the corresponding 4-fluoroglutamic acids. 470 Various chromatographic techniques have been used to resolve , amino acids and their derivatives. 473 A new -basic chiral stationary phase has been proposed for the separation of amino acid enantiomers by liquid chromatography.

142 The preparation (and applications) of phenylalanine143 and -threonine144 have been reported. 146 In this study, the thermochemical aspects of the conversion of the gaseous system CO2—N2—H2O into a solid amino acid condensate in an electric discharge plasma are considered. 152 The synthesis of common naturally occurring amino acids and their derivatives has been widely reported. 161 The syntheses of [ring-14C]--tyrosine from [U-14C]-phenol,162 and other isotopically-labelled amino acids, including 2,3,4,2,3,5,6-2H7--tyrosine163 and 3,3,4,4,3,3,4,4-2H8-homocystine,164 have been reported.

256 N -(4-bromopyrrolyl-2-carbonyl)--homoarginine (26), a natural product from the sponge Agelas wiedenmayeri, has been synthesised from lysine. 6 Synthesis of -( -Halogeno-alkyl) -Amino Acids. 260 The syntheses of fluoro and difluoroalanines, using tris(diethylamino)-N-methylphosphazene for the fluoromethylation of diethyl N-acetylaminomalonate by CH2BrF or CHClF2 in DCM,261 3,3-difluoroserine and -cysteine derivatives via Mg(0)-promoted selective C—F bond cleavage of trifluoromethyl imines,262 cis-4-[18F]fluoro--proline and trans-4-[18F]fluoro--proline have been synthesised via a semi-automated, NCA procedure using the General Electric FDG microlab, a system employing a quaternary 4-aminopyridinium resin to effect F-18 fluorination,263 and -difluoromethyl prolines and -aminoadipic acids by trapping reactions of in situ generated N-protected -methyl difluoroalaninyl radicals264 have been reported.

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Amino Acids, Peptides and Proteins (SPR Amino Acids, Peptides, and Proteins (RSC)) (Vol 33) by G. C. Barrett, J. S. Davies

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