By F.G.A. Stone, Robert West (Eds.)
ADVANCES ORGANOMETALLIC CHEMISTRY V12. content material: bankruptcy 7. The Literature of Organo-Transition steel Chemistry 1972Author Index: experiences of Organo-Transition steel Chemistry; writer Index; topic Index; Cumulative record of individuals; Cumulative record of Titles. summary: ADVANCES ORGANOMETALLIC CHEMISTRY V12
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2433 (1964), and references therein. 22. , and Davidson, J. , J. Chem. 843 (1965). 23. , Duncanson, L. , Shaw, B. , and Venanzi, L. Dis. 26,131 (1958),and references therein. 24. , Duncanson, L. , and Shaw, B. , Proc. Chem. , and Shaw, B. , J. Chem. 5075 (1962). 25. , Guy, R. , Duncanson, L. , and Thompson, D. , J. Chem. SOC. 5170 (1963), and references therein. 26. , and Venanzi, L. , J. Chem. SOC. 4456,4461 (1955). 27. , Ibekwe, S. , and Kapoor, P. ,J. , A, 1343 (1970). 28. , and Hayter, R. , J.
71 71 * 7 2 72 * * . . . . . 73 74 74 74 75 75 75 76 . 7 7 List of Abbreviations The following abbreviations, listed alphabetically, will be used in the text and in the tables : bae N,N'-Ethylenebis(acetylacetony1iminato) n-Bu n-Butyl CP h6-Cyclopentadienyl(but not hl-CsH8) CPr Cyclopropyl dipy 2,2'-Bipyridine DMF N,N-Dimethylformamide dmgH Dimethylglyoximato Et Ethyl Ind h6-Indenyl isoquin Isoquinoline L Monodentate ligand (usually nonionic) Metal (sometimes with ancillary ligands) M Me Methyl Me,Cp x-Methyl-substituted h%yclopentadienyl Naph Naphthyl Ph Phenyl o-phen 1,lo-Phenanthroline Pr Propyl PY Pyridine R,R',R" Hydrocarbon radicals h5-Cyclopentadienylwith x substituents R' R'XP salen N,W-Ethylenebis(salicy1aldiminato) salophen N,W-Phenylenebis (salicylaldiminato) THF Tetrahydrofuran X Halogen, pseudohalogen, or a similar group Sulfur Dioxide Insertion Reactions 33 I INTRODUCTION This is the second chapter of a two-part review concerned with insertion reactions of transition metal-carbon o-bonded compounds.
Accordingly, MeOS(0)Ir(CO)(PMePh2),C12 absorbs at a lower field than MeS(0)21r(CO)(PMePh2),C12 (54); in contrast, a number of 0-sulfinates of CpFe(CO),, CpMo(CO),, Mn(CO),, and Re(CO), show resonances at higher fields than the corresponding S-sulfinates (73). Structures of several transition metal sulfinates, o k , (Me,Cp)Fe(CO),S(O),CH,CH=CHPh (24), CpFe(CO),S(0),C6F, (27),MeS(0)2Mn(CO),dipy (124, and CU(H,O)~[OS(O)C,H~M~-~]~ (89), have been determined by X-ray crystallography. In each case, the mode of metalsulfinate bonding is that inferred from spectroscopic data (110,43, 68, 39, respectively).
Advances in Organometallic Chemistry, Vol. 12 by F.G.A. Stone, Robert West (Eds.)